Flory-rehner方程
Web512 P. J. FLORY AND J. REHNER, JR. Equation (12) was used to find the curves shown in Fig. 1. The rate expression involving the acid chro mate ion is -d(Cr03)/dt = k(HCr04-) (CH3CHOHCH3) (H+)2. (6) The concentration of acid chromate ion can be calculated from the equilibrium expression where the parentheses indicate concentrations, Web因此,作者扩展了经典的Flory-Rehner水凝胶溶胀理论,将其与赫兹接触力学相耦合,明确地处理了介质在水凝胶颗粒接触处产生的应力。 3、利用这种方法,作者表明,水凝胶的膨胀程度取决于水凝胶施加的渗透膨胀力与周 …
Flory-rehner方程
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WebThe phase coexistence observed around the first-order transition in NIPA gels cannot be interpreted by the Flory-Rehner theory because this theory tacitly assumes that the equilibrium state of a gel is always a homogeneous one. Heterogeneous structures such as two-phase coexistence are ruled out from the outset in this theory. Of course, if the … http://polymerdatabase.com/polymer%20physics/Flory%20Rehner.html
Web胀程度与交联密度满足Flory-Rehner公式[12]: () (1) ln v VV f V VV V 2 1 / 0 13 2 r r = rr r-- ++ 式中,v为橡胶交联密度,V r为溶胀样品中橡胶体积 分数,χ为橡胶与溶剂相互作用参 … http://www.physics.emory.edu/faculty/roth/polymercourse/historical/Flory_JCP43.pdf
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Web水凝胶的弹性和断裂行为都受其含水量的影响。大量的实验数据显示,目前基于平均场假设的Flory-Rehner理论(F-R理论)具有一些局限性,无法正确地描述含水量(或与之对应的聚合物分数)的变化对水凝胶弹性模量的影响。
Web在1940年代初期,Paul Flory和John Rehner发表了有关可膨胀聚合物网络特性的一系列论文。它们最初的用途是硫化橡胶,此后被广泛使用并扩展到更复杂的系统(例如水凝 … grandview vs lindsey wilson footballWebOct 1, 1990 · The Frenkel-Flory-Rehner (FFR) hypothesis that the elastic free energy of a swollen network is balanced by the free energy of mixing has been examined using experiments on dicumyl peroxide ... grandview vision centerWebIn this paper, we explain the increased swelling of crosslinked polysaccharide microgels by the increase of sugar concentration using a modified Flory–Rehner theory. This theory … chinese take out buffetWebFlory-Rehner(F-R)モデル (1)が基礎的かつよく知られている (2),(3).この自由エネルギー関数は,統計分子鎖理論に基づく Neo-Hookean 型の弾性ひずみエネルギーと Flory-Huggins 理 論に基づく混合エネルギーの線形和で構成される.したがっ chinese take out container sizesWeb522 P. J. FLORY AND J. REHNER, JR. bining these, there is obtained the total entropy of mixing of solvent with cross-linked polymer, from which activities of solvent and the swelling limit can be computed, as well as their depend ence on the structure of the network. THE ENTROPY OF SWELLING Paralleling the procedure followed in the pre chinese take out center morichesWebフローリー‐レーナーの式【Flory-Rehner equation】. 架橋高分子ゲルの 膨潤 に関する理論式である.膨潤平衡に達したゲル相中の高分子の容積分率を v2 ,高分子溶媒相互作用定数を χ 1 ,溶媒の 分子容 を V1 ,高分子の 比容 を v ,架橋点間の 分子量 を Mc ... grandview vineyard mt joy imagesIn polymer science Flory–Rehner equation is an equation that describes the mixing of polymer and liquid molecules as predicted by the equilibrium swelling theory of Flory and Rehner. It describes the equilibrium swelling of a lightly crosslinked polymer in terms of crosslink density and the quality of the solvent. The … See more The Flory–Rehner theory gives the change of free energy upon swelling of the polymer gel similar to the Flory–Huggins solution theory: The theory … See more • Flory, Paul; Rehner, John (1943). "Statistical mechanics of cross-linked polymer networks II. Swelling". J. Chem. Phys. 11 … See more grandview vision center columbus